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This is a list of characters from the light novel series Toaru Majutsu no Index as well as its manga adaptation, spin-off manga (Toaru Kagaku no Railgun), and both series' anime adaptations. The series primarily takes place in Academy City, a city filled with students who strive to become powerful espers, which is brought into conflict by the appearance of magicians.

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: is the series' main protagonist. His parents are Tōya and Shiina Kamijō. He tends to stay away from trouble but possesses a strong sense of justice. He is a smart student and knowledgeable about certain subjects yet is a failure in his esper studies. While he is an idealist for the hopes of other people, ironically he is cynical about himself possibly because of his powers.

: His right hand contains a power he calls , a power which negates all magic, psychic, or divine powers but also his own good luck ("divine providence" as defined by Index). Because this ability can not be detected through testing, he has been given the lowest psychic rank, Level 0. Due to the nature of his power, the founder of Academy City considers him neither a Psychic nor a Magician but rather a normal person with a unique ability.

Shirai Kuroko has not been a contender in any CBUB matches.